Novel process for generating useful electrophiles from common anions using Selectfluor® fluorination agent
…, TP Nguyen, VL Bulleck, RD Rieth
Index: Syvret, Robert G.; Butt, Kathleen M.; Nguyen, Tung P.; Bulleck, Victoria L.; Rieth, Ryan D. Journal of Organic Chemistry, 2002 , vol. 67, # 13 p. 4487 - 4493
Full Text: HTML
Citation Number: 51
Abstract
In the present work, the electrophile equivalents Cl+, Br+, SCN+, and NO2+ are generated from their respective sodium, potassium, and in some cases ammonium salts (M+ X-) by reaction with Selectfluor electrophilic fluorination agent in acetonitrile solution at room temperature. These generated electrophilic species subsequently react in situ with a variety of aromatic substrates containing one or more substituent groups including H, F, Cl, CH3, ...
Related Articles:
Cu (I)/Cu (II)/TMEDA, new effective available catalyst of sandmeyer reaction
[Sigeev, A. S.; Beletskaya, I. P.; Petrovskii, P. V.; Peregudov, A. S. Russian Journal of Organic Chemistry, 2012 , vol. 48, # 8 p. 1055 - 1058,4 Zhurnal Organicheskoi Khimii, 2012 , vol. 48, # 8 p. 1059 - 1062,4]
[Khazaei, Ardeshir; Alizadeh, Abdolhamid; Vaghei, Ramin Ghorbani Molecules, 2001 , vol. 6, # 3 p. 253 - 257]
[Takagi, Kentaro; Takachi, Hideaki; Sasaki, Ken Journal of Organic Chemistry, 1995 , vol. 60, # 20 p. 6552 - 6556]
[Barbero; Degani; Diulgheroff; Dughera; Fochi Synthesis, 2001 , # 4 p. 585 - 590]
[Harusawa, Shinya; Shioiri, Takayuki Tetrahedron Letters, 1982 , vol. 23, # 4 p. 447 - 448]