Allylic Rearrangements. XIII. Kinetics and Mechanisms of the Conversion of Crotyl and Methylvinylcarbinyl Chlorides to Acetates and Ethyl Ethers1

JD Roberts, WG Young, S Winstein

Index: Roberts; Young; Winstein Journal of the American Chemical Society, 1942 , vol. 64, p. 2163

Full Text: HTML

Citation Number: 35

Abstract

Sept., 1942 ALLYLIC CONVERSION OF CROTYL AND METHYLVINYLCARBINYL CHLORIDES 2 157 water was added and the gummy product recrystallized from alcohol yielding 1.3 g.(60%'0), m. P. 139-141'. A mixed melting point of this synthetic material with Schorigin's compound showed no depression. Anal. Calcd. for CasH~ oOI: C, 87.1; H, 6.27. Found: C, 86.8; H, 6.30. diphenylmethyl group under mild conditions involves the para ...