Synthesis and characterization of two cyanoxime ligands, their precursors, and light insensitive antimicrobial silver (I) cyanoximates
…, M Patrauchan, S Silchenko, N Gerasimchuk
Index: Riddles, Courtney N.; Whited, Mark; Lotlikar, Shalaka R.; Still, Korey; Patrauchan, Marianna; Silchenko, Svitlana; Gerasimchuk, Nikolay Inorganica Chimica Acta, 2014 , vol. 412, p. 94 - 103
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Citation Number: 3
Abstract
Abstract High-yield syntheses of N-piperidine-cyanacetamide (1), N-morpholyl- cyanacetamide (4) and their oxime derivatives N-piperidine-2-cyano-2-oximino-acetamide (HPiPCO, 2) and N-morpholyc-2-cyano-2-oximino-acetamide (HMCO, 5) were developed using two-step preparations. At first, the reactions of neat cyanoacetic acid esters and the respective cyclic secondary amines such as piperideine and morpholine afforded pure ...
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