Synthesis of biaryls via nickel-catalyzed cross-coupling reaction of arylboronic acids and aryl mesylates
M Ueda, A Saitoh, S Oh-tani, N Miyaura
Index: Ueda, Masato; Saitoh, Atsushi; Oh-tani, Saori; Miyaura, Norio Tetrahedron, 1998 , vol. 54, # 43 p. 13079 - 13086
Full Text: HTML
Citation Number: 77
Abstract
The cross-coupling reaction of arylboronic acids (1.3 equivs) with aryl methane-sulfonates was carried out in the presence of a nickel (0) catalyst (3 mol%) and K3PO4· nH2O (3 equivs). The use of toluene as the solvent and the nickel (0)-dppf catalyst prepared from NiCl2 (dppf) plus dppf with BuLi were recognized to be the most efficient to achieve both high yields and high selectivity. The reaction can be applied to various electron-deficient ...
Related Articles:
[Tanaka, Shinya; Kaneko, Tetsuro; Asao, Naoki; Yamamoto, Yoshinori; Chen, Mingwei; Zhang, Wei; Inoue, Akihisa Chemical Communications, 2011 , vol. 47, # 21 p. 5985 - 5987]
A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids
[Mo, Fanyang; Qiu, Di; Jiang, Yubo; Zhang, Yan; Wang, Jianbo Tetrahedron Letters, 2011 , vol. 52, # 4 p. 518 - 522]
[Inada, Kaoru; Miyaura, Norio Tetrahedron, 2000 , vol. 56, # 44 p. 8657 - 8660]
[Shirakawa, Eiji; Itoh, Ken-Ichi; Higashino, Tomohiro; Hayashi, Tamio Journal of the American Chemical Society, 2010 , vol. 132, # 44 p. 15537 - 15539]
Plasmonic harvesting of light energy for Suzuki coupling reactions
[Wang, Feng; Li, Chuanhao; Chen, Huanjun; Jiang, Ruibin; Sun, Ling-Dong; Li, Quan; Wang, Jianfang; Yu, Jimmy C.; Yan, Chun-Hua Journal of the American Chemical Society, 2013 , vol. 135, # 15 p. 5588 - 5601]