Effective Synthesis of 1, 3-Diselenole-2-selone-4, 5-diselenolate (dsis) and its Utilization for the Synthesis of Selenocycle-fused Tetraselenafulvalene (TSF) …

…, K Takimiya, Y Aso, T Otsubo, T Nakayashiki…

Index: Kodani; Takimiya; Aso; Otsubo; Nakayashiki; Misaki Synthesis, 2001 , # 11 p. 1614 - 1618

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Citation Number: 13

Abstract

In the field of organic conductors, 1,3-dithiole-2-thione-4,5-dithiolate (dmit, 1) is a very important compound both as a key intermediate for the synthesis of thio-substituted tetrathiafulvalene (TTF)-type electron donors and as a ligand for metal complexes of M(dmit) 2 type. [1] Indeed, a great number of organic conductors and superconductors have been produced from the TTF-type donors and the M(dmit) 2 metal complexes. [2] In such organic conductors and ...