Preparation and some reactions of bis (thioacyl) sulfides

…, H Shibahashi, T Katada, T Takagi…

Index: Kato, Shinzi; Shibahashi, Hiroshi; Katada, Tomonori; Takagi, Takashi; Noda, Ippei; et al. Liebigs Annalen der Chemie, 1982 , # 7 p. 1229 - 1244

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Citation Number: 21

Abstract

Abstract Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis (thioacyl) sulfides 1 in good yield, which are very useful thioacylating reagents under mild reaction conditions. Most of the aromatic thioanhydrides (1, R= aromatic) are fairly stable green crystals at room temperature, but the aliphatic ones (1, R= aliphatic) are unstable purple oils which dimerize at room temperature to give the ...

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