Reaction of Methanesulfonic Anhydride with Hydrogen Halides1

L Field, PH Settlage

Index: Field; Settlage Journal of the American Chemical Society, 1955 , vol. 77, p. 170

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Citation Number: 4

Abstract

anol and titanium tetrachloride in the presence of amm~ nia.~ This siloxy titane is a water- whiteJ mobile liquid which boils at 106'at 7 mm., almost the same boiling point as t-butoxy titanate, 108'at 10 mm. 8 In this connection it is interesting to note that hexamethyldisiloxane boils at 100'and di-t-butyl ether boils at 101 O, lo both at atmospheric pressure.