Journal of Materials Chemistry

Novel high-T g poly (amine-imide) s bearing pendent N-phenylcarbazole units: synthesis and photophysical, electrochemical and electrochromic properties

GS Liou, SH Hsiao, HW Chen

Index: Liou, Guey-Sheng; Hsiao, Sheng-Huei; Chen, Hwei-Wen Journal of Materials Chemistry, 2006 , vol. 16, # 19 p. 1831 - 1842

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Citation Number: 126

Abstract

A new carbazole-derived, triphenylamine-containing aromatic diamine monomer, 4, 4′- diamino-4 ″-N-carbazolyltriphenylamine, was successfully synthesized by the caesium fluoride-mediated condensation of N-(4-aminophenyl) carbazole with 4-fluoronitrobenzene, followed by palladium-catalyzed hydrazine reduction. A series of novel poly (amine-imide) s 6a–6g with pendent N-phenylcarbazole units having inherent viscosities of 0.17–0.56 dL ...

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