π-Extended and Six-Coordinate Iron (II) Complexes: Structures, Magnetic Properties, and the Electrochemical Synthesis of a Conducting Iron (II) Metallopolymer

…, T Seda, SI Gorelsky, AJ Lough, MT Lemaire

Index: Djukic, Brandon; Seda, Takele; Gorelsky, Serge I.; Lough, Alan J.; Lemaire, Martin T. Inorganic Chemistry, 2011 , vol. 50, # 15 p. 7334 - 7343

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Citation Number: 10

Abstract

The synthesis of three new π-extended derivatives of the ligand ppi are reported, including the structural and magnetic properties of three iron (II) complexes containing these ligands. Two of the complexes exhibit spin-crossover, and another features unusual temperature dependent magnetic behavior. We also describe the electrochemical synthesis and magnetic and charge transport properties of a metallopolymer from one of the precursor ...