Tetrahedron

Epoxydation en milieu heterogene solide-liquide faiblement hydrate: Etude des interactions moleculaires: sel de sulfonium-base

ME Borredon, JV Sinisterra, M Delmas, A Gaset

Index: Borredon, M. E.; Sinisterra, J. V.; Delmas, M.; Gaset, A. Tetrahedron, 1987 , vol. 43, # 18 p. 4141 - 4146

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Abstract

Résumé Structural analysis of the solid-liquid interface topography in relation to the reaction of the sulfonium salt considered and furfural allows definition of the nature of the acid-base interactions that result predominately in formation of the 2-furyl oxiran. Moreover the study made with KOH H 2 O; Ba (OH) 2 0, 8 H 2 O and K 2 CO 3 1, 5 H 2 O in the solid state pointed out that compatibility between the crystalline lattice of the solid phase and the ...

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