Copper-catalyzed decarboxylative coupling of aryl halides with alkynyl carboxylic acids performed in water
T Li, P Sun, H Yang, Y Zhu, H Yan, L Lu, J Mao
Index: Li, Tingyi; Sun, Peng; Yang, Hailong; Zhu, Yan; Yan, Hong; Lu, Linhua; Mao, Jincheng Tetrahedron, 2012 , vol. 68, # 32 p. 6413 - 6419
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Citation Number: 16
Abstract
Most alkynes are volatile liquids, which are relatively difficult to use and to transport. In contrast, alkynyl carboxylic acids offer a stable and attractive alternative for the alkynylation reactions. Here, we employed alkynyl carboxylic acids as reaction partners for the alkynylation of aryl halides. Copper-catalyzed decarboxylative coupling, including various challenging aryl bromides with phenylpropiolic acid, was performed in water without using ...
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