Synthetic and kinetic studies on tricarbonates and dicarbonates

BM Pope, SJ Sheu, RL Stanley…

Index: Pope,B.M. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 2410 - 2414

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Citation Number: 14

Abstract

% D in 9Zfrom lib= kc where R= kdko for deprotonation of chlorolium ion 13; kc= rate constant for 12-13;= rate constant for 12-92, ka= rate constant for 12= kM/b, which is the isotope effect for deprotonation of vinyl cation 12. To solve these equations, it is necessary to assume a value for either R or fH/pO. Once the equatlon is solved, the fraction of 9 Z formed from chioroiium ion is given by 1/(1 t fH).