Palladium??Catalyzed Mono?螃窿?arylation of Carbonyl??Containing Compounds with Aryl Halides using DalPhos Ligands
…, PG Alsabeh, M Stradiotto
Index: Crawford, Sarah M.; Alsabeh, Pamela G.; Stradiotto, Mark European Journal of Organic Chemistry, 2012 , # 30 p. 6042 - 6050,9
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Citation Number: 15
Abstract
Abstract We report the extension and optimization of the [Pd (cinnamyl) Cl] 2/DalPhos catalyst system, previously found effective for the mono-α-arylation of acetone, to the mono-α- arylation of a variety of carbonyl-containing compounds with aryl halides and heteroaryl halides. Aryl methyl ketones, heteroaryl methyl ketones, propiophenones, malonates, and methoxyacetone can be α-arylated under relatively mild conditions and in good yields. We ...
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