Synergistic role of Lewis and Brönsted acidities in Friedel–Crafts alkylation of resorcinol over gallium-zeolite beta

…, Z Ramli, J Efendi, ANA Rahman, S Chandren…

Index: Nur, Hadi; Ramli, Zainab; Efendi, Jon; Rahman, Aiman Najati Akmar; Chandren, Sheela; Yuan, Lai Sin Catalysis Communications, 2011 , vol. 12, # 9 p. 822 - 825

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Citation Number: 24

Abstract

The role of Lewis and Brönsted acidities in alkylation of resorcinol is demonstrated through the gallium-zeolite beta by varying the amount of Lewis and Brönsted acid sites. The synergism of Lewis and Brönsted acid sites takes place heterogeneously in Friedel–Crafts alkylation of resorcinol with methyl tert-butyl ether to produce 4-tert-butyl resorcinol and 4, 6- di-tert-butyl resorcinol as the major and minor products, respectively.