Molecules

One-pot preparations of diaryliodonium bromides from iodoarenes and arenes, with sodium perborate as the oxidant

A Kryska, L Skulski

Index: Kryska, Anna; Skulski, Lech Molecules, 2001 , vol. 6, # 11 p. 875 - 880

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Citation Number: 22

Abstract

Abstract: This paper reports a one-pot synthesis of the title bromides from both activated and deactivated iodoarenes which are first oxidized with anhydrous NaBO 3· H 2 O/Ac 2 O/conc. H 2 SO 4 liquid mixtures, then coupled in situ with benzene and activated arenes and, finally, precipitated out with a KBr solution; this method is easy, cheap, safe and fairly effective.