A novel method for the separation of bis (α-hydroxyalkyl) phosphinic acid diastereoisomers via formation of novel cyclic phosphinic acids

B Kaboudin, H Haghighat…

Index: Kaboudin; Balakrishna Synthetic Communications, 2001 , vol. 31, # 18 p. 2773 - 2776

Full Text: HTML

Citation Number: 30

Abstract

The reaction of aromatic and aliphatic aldehydes with hypophosphorus acid under microwave irradiation was examined. The reaction gave a mixture of a racemic pair of bis (α- hydroxyalkyl) phosphinic acids and acetal derivatives from the corresponding bis (α-

Related Articles:

Synthesis of dialkyl and diaryl benzylphosphonates through a ZnI 2-mediated reaction

[Richardson, Rebekah M.; Barney, Rocky J.; Wiemer, David F. Tetrahedron Letters, 2012 , vol. 53, # 49 p. 6682 - 6684]

Copper??Catalyzed Synthesis of Alkylphosphonates from H??Phosphonates and N??Tosylhydrazones

[Miao, Wenjun; Gao, Yuzhen; Li, Xueqin; Gao, Yuxing; Tang, Guo; Zhao, Yufen Advanced Synthesis and Catalysis, 2012 , vol. 354, # 14-15 p. 2659 - 2664]

Photo-Arbuzov rearrangements of benzyl phosphites

[Omelanzcuk, Jan; Sopchik, Alan E.; Lee, Sueg-Geun; Akutagawa, Kunihiko; Cairns, Matthew S.; Bentrude, Wesley G. Journal of the American Chemical Society, 1988 , vol. 110, # 20 p. 6908 - 6909]

Palladium (0)-catalyzed benzylation of H-phosphonate diesters: an efficient entry to benzylphosphonates

[Laven, Gaston; Stawinski, Jacek Synlett, 2009 , # 2 p. 225 - 228]

Palladium (0)-catalyzed benzylation of H-phosphonate diesters: an efficient entry to benzylphosphonates

[Laven, Gaston; Stawinski, Jacek Synlett, 2009 , # 2 p. 225 - 228]

More Articles...