Inorganica Chimica Acta

A simple Ru catalyst for the conversion of aldehydes or oximes to primary amides

JF Hull, ST Hilton, RH Crabtree

Index: Hull, Jonathan F.; Hilton, Sheena T.; Crabtree, Robert H. Inorganica Chimica Acta, 2010 , vol. 363, # 6 p. 1243 - 1245

Full Text: HTML

Citation Number: 30

Abstract

Ru(DMSO) 4 Cl 2 is catalytically active for converting aldehydes to primary amides via oxime intermediates. This catalyst is readily available, and requires no additional ligands, a great simplification compared to previous work. A Ru(II)/(IV) mechanism is proposed. ... Ru(DMSO) 4 Cl 2 , containing only DMSO and Cl ligands, is catalytically active for the conversion of aldehydes and oximes to amides, with no additives. ... Amides, which are valuable intermediates in organic ...

Related Articles:

A general and practical oxidation of alcohols to primary amides under metal-free conditions

[Wu, Xiao-Feng; Sharif, Muhammad; Feng, Jian-Bo; Neumann, Helfried; Pews-Davtyan, Anahit; Langer, Peter; Beller, Matthias Green Chemistry, 2013 , vol. 15, # 7 p. 1956 - 1961]

A General Palladium??Catalyzed Aminocarbonylation of Phenols to Primary Benzamides via In Situ Generation of Aryl Nonaflates

[Wu, Xiao-Feng; Neumann, Helfried; Beller, Matthias Chemistry - A European Journal, 2012 , vol. 18, # 2 p. 419 - 422]

Synthesis and anthelmintic activity of 3'-benzoylurea derivatives of 6-phenyl-2, 3, 5, 6-tetrahydroimidazo [2, 1-b] thiazole

[Weikert; Bingham Jr.; Emanuel; Fraser-Smith; Loughhead; Nelson; Poulton Journal of Medicinal Chemistry, 1991 , vol. 34, # 5 p. 1630 - 1633]

Synthesis and anthelmintic activity of 3'-benzoylurea derivatives of 6-phenyl-2, 3, 5, 6-tetrahydroimidazo [2, 1-b] thiazole

[Weikert; Bingham Jr.; Emanuel; Fraser-Smith; Loughhead; Nelson; Poulton Journal of Medicinal Chemistry, 1991 , vol. 34, # 5 p. 1630 - 1633]

More Articles...