Stereochemistry of Diels-Alder Adducts. II. The Alkylation of Some Bicyclic Nitriles
WR Boehme, E Schipper, WG Scharpf…
Index: Boehme et al. Journal of the American Chemical Society, 1958 , vol. 80, p. 5488,5493
Full Text: HTML
Citation Number: 29
Abstract
The stereochemistry of some carboxylic acids derived from 2-norbornene* and bicyclo [2, 2, 2] oct-2-ene was investigated. The reaction of either 5-endocyano-2-norbornene (Ia) or 5- exocyano-2-norbornene (Ib) with methyl chloride in the presence of sodamide and liquid ammonia gave 5-endocyano-5-exomethyl-2-norbornene(111). As a by-product of both reactions, there was obtained an amidine fraction which upon saponification gave 2- ...
Related Articles:
[Fischer, Walter; Grob, Cyril A.; Sprecher, Georg von; Waldner, Adrian Helvetica Chimica Acta, 1980 , vol. 63, # 4 p. 928 - 937]
[Grob, Cyril A.; Herzfeld, Danielle Helvetica Chimica Acta, 1982 , vol. 65, # 8 p. 2443 - 2447]
[Grob, Cyril A.; Herzfeld, Danielle Helvetica Chimica Acta, 1982 , vol. 65, # 8 p. 2443 - 2447]
[Grob, Cyril A.; Herzfeld, Danielle Helvetica Chimica Acta, 1982 , vol. 65, # 8 p. 2443 - 2447]
[Grob, Cyril A.; Herzfeld, Danielle Helvetica Chimica Acta, 1982 , vol. 65, # 8 p. 2443 - 2447]