(pyridine)(tetrahydroborato) zinc complex mediated acetylation of amines with ethyl acetate
B Zeynizadeh, K Zahmatkesh
Index: Zeynizadeh, Behzad; Zahmatkesh, Karam Journal of the Chinese Chemical Society, 2004 , vol. 51, # 4 p. 801 - 805
Full Text: HTML
Citation Number: 22
Abstract
(Pyridine)(tetrahydroborato)zinc complex, (Py)Zn(BH4)2, can efficiently perform acetylation of a variety of aliphatic and aromatic amines with ethyl acetate under refluxing THF. ... Keywords: Acetylation; Amine; Acetamide; Zinc tetrahydroborate; Pyridine. ... The protection of amino groups by the formation of amides, especially acetamides, is one of the most fundamen- tal and widely used procedures in organic syntheses. This goal is often ...
Related Articles:
Convenient acylative dealkylation of tertiary amines
[Dave, Paritosh R.; Kumar, Kaipenchery A.; Duddu, Rajagopal; Axenrod, Theodore; Dai, Rongji; Das, Kajal K.; Guan, Xiao-Pei; Sun, Jianguang; Trivedi, Nirupam J.; Gilardi, Richard D. Journal of Organic Chemistry, 2000 , vol. 65, # 4 p. 1207 - 1209]
Microwaves-assisted solvent-free synthesis of N-acetamides by amidation or aminolysis
[Ferroud, Clotilde; Godart, Marie; Ung, Stephane; Borderies, Helene; Guy, Alain Tetrahedron Letters, 2008 , vol. 49, # 18 p. 3004 - 3008]
[Paul, Satya; Nanda, Puja; Gupta, Rajive; Loupy, Andre Tetrahedron Letters, 2002 , vol. 43, # 23 p. 4261 - 4265]