The Action of Elementary Fluorine upon Organic Compounds. XXVII. The Direct Fluorination of Fluorinated Aliphatic Dinitriles

BC Bishop, JB Hynes, LA Bigelow

Index: Bishop et al. Journal of the American Chemical Society, 1963 , vol. 85, p. 1606

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Citation Number: 11

Abstract

CF3CFzCFz CFsNFz. NF2 and the final production of n-CkFgNF2. On the other hand, the original adduct might undergo cleavage with the formation of FCN and CF3CF2CF= N.. The latter would then undergo alkylation by CFzN= N. itself produced by the fluorination of FCN through the nitrene and azo dimer. 3 This would give first the isolated unsaturate CF3N= CFC? F~ and finally its saturated analog. Similar schemes may readily be set up for the ...