General Method for the Synthesis of Salicylic Acids from Phenols through Palladium??Catalyzed Silanol??Directed C H Carboxylation

Y Wang, V Gevorgyan

Index: Sarkar, Dhruba; Melkonyan, Ferdinand S.; Gulevich, Anton V.; Gevorgyan, Vladimir Angewandte Chemie - International Edition, 2013 , vol. 52, # 41 p. 10800 - 10804 Angew. Chem., 2013 , vol. 125, # 41 p. 11000 - 11004,5

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Citation Number: 13

Abstract

Abstract A silanol-directed, palladium-catalyzed C [BOND] H carboxylation reaction of phenols to give salicylic acids has been developed. This method features high efficiency and selectivity, and excellent functional-group tolerance. The generality of this method was