A new method for the reduction of isocyanates to isocyanides
JE Baldwin, JC Bottaro, PD Riordan…
Index: Baldwin, Jack E.; Bottaro, Jeffrey C.; Riordan, Peter D.; Derome, Andrew E. Journal of the Chemical Society, Chemical Communications, 1982 , # 16 p. 942 - 943
Full Text: HTML
Citation Number: 9
Abstract
Both diphenyl-t-butylsilyl-lithium and trichlorosilane-triethylamine reduce isocyanates to isocyanides in high yield under mild conditions. ... The literature contains few methods for reducing isocyanates to isocyanides, equation ( l). While simple phosphines and ... Published on 01 January 1982. Downloaded by google on 21/02/2016 10:41:00. ... View Article Online / Journal Homepage / Table of Contents for this issue ... 7 The use of di-isopropylethylamine gives slightly ...
Related Articles:
Dehydration of formamides using the Burgess Reagent: a new route to isocyanides
[Creedon, Siobhan M.; Crowley, H. Kevin; McCarthy, Daniel G. Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 6 p. 1015 - 1017]
[Guirado, Antonio; Zapata, Andres; Fenor, Manuel Tetrahedron Letters, 1992 , vol. 33, # 33 p. 4779 - 4782]
[Ley, Steven V; Taylor, Stephen J Bioorganic and medicinal chemistry letters, 2002 , vol. 12, # 14 p. 1813 - 1816]
Deoxygenation of isocyanates to isonitriles: A mechanistic study by nuclear magnetic resonance
[Tetrahedron, , vol. 39, # 18 p. 2989 - 2994]
[Tetra (2, 3??pyrido) porphyrazinato] eisen (II)??Verbindungen mit Isocyaniden als axialen Liganden
[Chemische Berichte, , vol. 121, p. 1225 - 1230]