Tetrahedron

A novel type of PdMC-catalyzed hydrogenation using a catalyst poison: Chemoselective inhibition of the hydrogenolysis for O-benzyl protective group by the addition …

H Sajiki, K Hirota

Index: Sajiki, Hironao; Hirota, Kosaku Tetrahedron, 1998 , vol. 54, # 46 p. 13981 - 13996

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Citation Number: 143

Abstract

A mild and chemoselective hydrogenation method for a variety of reducible functional groups distinguishing from aliphatic and aromatic benzyl ethers was accomplished by the addition of an appropriate nitrogen-containing base to the Pd/C-catalyzed hydrogenation system.