Enzymatic synthesis of symmetrical 1, 3-diacylglycerols by direct esterification of glycerol in solvent-free system
R Rosu, M Yasui, Y Iwasaki, T Yamane
Index: Rosu, Roxana; Yasui, Mamoru; Iwasaki, Yugo; Yamane, Tsuneo JAOCS, Journal of the American Oil Chemists' Society, 1999 , vol. 76, # 7 p. 839 - 843
Full Text: HTML
Citation Number: 111
Abstract
Abstract 1, 3-Diacylglycerols were synthesized by direct esterification of glycerol with free fatty acids in a solvent-free system. Free fatty acids with relatively low melting points (< 45° C) such as unsaturated and medium-chain saturated fatty acids were used. With stoichiometric ratios of the reactants and water removal by evaporation at 3 mm Hg vacuum applied at 1 h and thereafter, the maximal 1, 3-diacylglycerol content in the reaction ...
Related Articles:
Synthesis and tandem mass spectrometry of chlorinated triacylglycerols
[Lefsay, Abir M.; Guy, Robert D.; Chatt, Amares; White, Robert L. Chemistry and Physics of Lipids, 2013 , vol. 174, p. 55 - 63]
LDH-catalyzed esterification of lauric acid with glycerol in solvent-free system
[Hamerski, Fabiane; Corazza, Marcos L. Applied Catalysis A: General, 2014 , vol. 475, p. 242 - 248]
[Cauvel, Anne; Renard, Gilbert; Brunel, Daniel Journal of Organic Chemistry, 1997 , vol. 62, # 3 p. 749 - 751]
LDH-catalyzed esterification of lauric acid with glycerol in solvent-free system
[Hamerski, Fabiane; Corazza, Marcos L. Applied Catalysis A: General, 2014 , vol. 475, p. 242 - 248]
[Ghandi, Mehdi; Mostashari, Abdoljalil; Karegar, Mojgan; Barzegar, Mina JAOCS, Journal of the American Oil Chemists' Society, 2007 , vol. 84, # 7 p. 681 - 685]