Substrate profile of an ω-transaminase from Burkholderia vietnamiensis and its potential for the production of optically pure amines and unnatural amino acids

J Jiang, X Chen, J Feng, Q Wu, D Zhu

Index: Jiang, Jinju; Chen, Xi; Feng, Jinhui; Wu, Qiaqing; Zhu, Dunming Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 100, p. 32 - 39

Full Text: HTML

Citation Number: 2

Abstract

Abstract A new (S)-enantioselective ω-transaminase (ω-TA) gene from Burkholderia vietnamiensis G4 was functionally expressed in Escherichia coli BL21 (DE3), and the purified recombinant N-terminal His-tagged ω-TA (HBV-ω-TA) had a dimeric structure with optimum pH and temperature of 8.4 and 40 C, respectively. The enzyme showed higher activities toward aromatic amines than aliphatic amines and (S)-1-methylbenzylamine ((S) ...

Related Articles:

Asymmetric Synthesis of. BETA.-Amino Acids by Addition of Chiral Enolates to Nitrones via N-Acyloxyiminium Ions.

[Kawakami; Ohtake; Arakawa; Okachi; Imada; Murahashi Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 11 p. 2423 - 2444]

Resolution of 1-arylalkylamines with 6-(1, 2: 3, 4-di-O-isopropylidene-α-d-galactopyranosyl) hydrogen phthalate

[Mereyala, Hari Babu; Fatima, Liyakat; Pola, Pallavi Tetrahedron Asymmetry, 2004 , vol. 15, # 4 p. 585 - 587]

Enantioselective reduction of oxime ethers with borane catalyzed by polymer-supported 2-piperazinemethanol

[Itsuno, Shinichi; Matsumoto, Takeshi; Sato, Daisuke; Inoue, Tsutomu Journal of Organic Chemistry, 2000 , vol. 65, # 18 p. 5879 - 5881]

Chiral azole derivatives, 3. Synthesis of the enantiomers of the potent aromatase inhibitor 1-[2-benzofuranyl (4-chlorophenyl) methyl]-1H-imidazole

[Messina, Flavia; Botta, Maurizio; Corelli, Federico; Mugnaini, Claudia Tetrahedron Letters, 1999 , vol. 40, # 40 p. 7289 - 7292]

Asymmetric Synthesis of. BETA.-Amino Acids by Addition of Chiral Enolates to Nitrones via N-Acyloxyiminium Ions.

[Kawakami; Ohtake; Arakawa; Okachi; Imada; Murahashi Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 11 p. 2423 - 2444]

More Articles...