Nitrosoalkane complexes of iron-porphyrins: Analogy between the bonding properties of nitrosoalkanes and dioxygen

D Mansuy, P Battioni, JC Chottard…

Index: Mansuy; Battioni; Chottard; Riche; Chiaroni Journal of the American Chemical Society, 1983 , vol. 105, # 3 p. 455 - 463

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Citation Number: 70

Abstract

Abstract: Various iron-porphyrin complexes involving an iron-nitrosoalkane bond, Fe"(porphyrin)(RNO)(L), with porphyrin= TPP, TpCIPP, TTP, or DPDME, R= i-Pr or Me, and L= MeOH, i-PrNHOH, i-PrNH,, pyridine, N-methylimidazole, or PPhMe2,'have been prepared either by reaction of Fe"(porphyrin) with the RNO dimer or of Fe"'(porphyrin)(CI) with RNHOH, in the presence of the L ligand. These hexacoordinate complexes and the ...