Chiral Co (II) Metal–Organic Framework in the Heterogeneous Catalytic Oxidation of Alkenes under Aerobic and Anaerobic Conditions
…, G Giambastiani, S Kwon, PC Stair, RQ Snurr…
Index: Tuci, Giulia; Giambastiani, Giuliano; Kwon, Stephanie; Stair, Peter C.; Snurr, Randall Q.; Rossin, Andrea ACS Catalysis, 2014 , vol. 4, # 3 p. 1032 - 1039
Full Text: HTML
Citation Number: 11
Abstract
The chiral Co (II) MOF [Co (l-RR)(H2O)· H2O]∞[1; l-RR=(R, R)-thiazolidine-2, 4- dicarboxylate] has been exploited in the catalytic oxidation of different alkenes (cyclohexene,(Z)-cyclooctene, 1-octene) using either tert-butyl hydroperoxide (t BuOOH) or molecular oxygen (O2) as oxidants. Different chemoselectivities are observed, both substrate-and oxidant-dependent. A moderate enantioselectivity is also obtained in the ...
Related Articles:
[Mekhaev; Pestov; Molochnikov; Kovaleva; Pervova; Yaltuk, Yu. G.; Grigor'Ev; Kirilyuk Russian Journal of Physical Chemistry A, 2011 , vol. 85, # 7 p. 1155 - 1161]
[Mitsudome, Takato; Sueoka, Shoichiro; Ikeda, Satoshi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi ChemCatChem, 2013 , vol. 5, # 10 p. 2879 - 2882]
[Mekhaev; Pestov; Molochnikov; Kovaleva; Pervova; Yaltuk, Yu. G.; Grigor'Ev; Kirilyuk Russian Journal of Physical Chemistry A, 2011 , vol. 85, # 7 p. 1155 - 1161]
[Mekhaev; Pestov; Molochnikov; Kovaleva; Pervova; Yaltuk, Yu. G.; Grigor'Ev; Kirilyuk Russian Journal of Physical Chemistry A, 2011 , vol. 85, # 7 p. 1155 - 1161]
[Schomaker, Jennifer M.; Pulgam, Veera Reddy; Borhan, Babak Journal of the American Chemical Society, 2004 , vol. 126, # 42 p. 13600 - 13601]