Tetrahedron Letters

Stereospecific nickel and phase transfer catalyzed carbonylation of vinyl bromides and chlorides

H Alper, I Amer, G Vasapollo

Index: Alper, Howard; Amer, Ibrahim; Vasapollo, Giuseppe Tetrahedron Letters, 1989 , vol. 30, # 20 p. 2615 - 2616

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Citation Number: 15

Abstract

... Ottawa Ottawa, Ontario, Canada K1N 6N5. Giuseppe Vasapollo. Centro MISO del CNR, Department of Chemistry University of Bari, 70126, Bari, Italy. Received 6 February 1989, Available online 9 March 2001. Abstract. Nickel cyanide catalyzes the carbonylation of vinyl bromides and chlorides to α,β-unsaturated acids. Vinyl bromides and chlorides are carbonylated to acids using Ni(CN) 2 as the catalyst. ... 3; I. Amer, H. Alper; J. Org. Chem., 53 (1988), p. 5147. ...

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