Tetrahedron letters

Alpha-deuterium isotope effects in the thermolysis of β-hydroxy esters

…, I Restrepo, LH Gallego, M del Socorro Yepes

Index: Quijano, Jairo; Restrepo, Iliana; Gallego, Luis H.; Yepes, M. del Socorro Tetrahedron Letters, 1994 , vol. 35, # 27 p. 4735 - 4738

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Citation Number: 10

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Alpha secondary isotope effects are determined experimentally by thermolysis of β-hydroxy esters. These results are compatible with a change of hybridization of carbon-2 from reactant to transition state (sp 3 - sp 2 ). ... A change of hybridization of C-2 (sp 3 → sp 2 ) in the ...