New metal–organic frameworks from triptycene: structural diversity from bulky bridges
AK Crane, BO Patrick, MJ MacLachlan
Index: Crane, Angela K.; Patrick, Brian O.; MacLachlan, Mark J. Dalton Transactions, 2013 , vol. 42, # 22 p. 8026 - 8033
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Citation Number: 11
Abstract
Four distinct triptycene-containing metal–organic frameworks, including three that are structural isomers, were synthesized and characterized. Structural isomerism was observed in the secondary building units of TMOF-2 giving rise to no fewer than three distinct [Zn4O] 6+ clusters. Structural integrity upon guest solvent removal was confirmed using powder X- ray diffraction and thermogravimetric analysis, but gas adsorption experiments were ...
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