C??nitroso compounds. Part XII: Cis??and trans??azodioxy compounds (dimeric nitroso compounds) by photochemical nitrosation of hydrocarbons with tert??butyl nitrite

A Mackor, TJ De Boer

Index: Mackor,A.; de Boer,T.J. Recueil des Travaux Chimiques des Pays-Bas, 1970 , vol. 89, p. 151 - 158

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Citation Number: 7

Abstract

Abstract The photochemical nitrosation of (cyclo) alkanes and alkylbenzenes, containing abstractable primary or secondary hydrogen atoms, with t-butyl nitrite has been carried out at 0-5 C using wavelengths around 400 nm. The main products are trans-azodioxy compounds (trans-dimeric nitroso compounds), derived from the solvent and the corresponding oximes in (total) yields, ranging from 55-80%. At low temperature or with ...