Oxidative cleavage of silicon-carbon bond with trimethylamine-N-oxide. New access to primary alcohols and aldehydes from terminal alkenes and alkynes
H Sakurai, M Ando, N Kawada, K Sato, A Hosomi
Index: Sakurai, Hideki; Ando, Masatomo; Kawada, Nobuo; Sato, Kazuhiko; Hosomi, Akira Tetrahedron Letters, 1986 , vol. 27, # 1 p. 75 - 76
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Citation Number: 18
Abstract
Abstract Oxidative cleavage of carbon-silicon bond of organosilanes with trimethylamine-N- oxide is achieved under mild conditions. The reaction occurs chemoselectively irrespective of the presence of amino and thio groups to give formally anti-Markovnikov hydration products of l-alkenes and l-alkynes via hydrosilylation.
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