Anomalous Reduction of Malonic Esters with Lithium Aluminum Hydride

WJ Bailey, ME Hermes, WA Klein

Index: Bailey,W.J. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 1724 - 1725

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Citation Number: 9

Abstract

as previously described6 and the forerun from the reductive acetylation was examined carefully. From this reduction was obtained a l5Y0 yield of 2, 3-di (acetoxymethyl)-3-butenyl acetate, together with the expected tetraacetate. The structure of this olefin triacetate was proved by pyrolysis to the known 2, 3-di (acetoxymethyl)-1, 3-butadiene6 and by independent synthesis by the pyrolysis of 2, 3-di (acetoxymethyl)-1, 4-diace-toxybutane. ...