Tetrahedron Letters

Rhenium-catalyzed reaction of carbonyl compounds with ketene silyl acetals

Y Nishiyama, K Kaiba, R Umeda

Index: Nishiyama, Yutaka; Kaiba, Kenta; Umeda, Rui Tetrahedron Letters, 2010 , vol. 51, # 5 p. 793 - 795

Full Text: HTML

Citation Number: 11

Abstract

It was found that rhenium complex is an effective catalyst for the reaction of carbonyl compounds with ketene silyl acetals. A wide range of β-silyloxy esters is obtained by the treatment of carbonyl compounds with ketene silyl acetals in the presence of a catalytic amount of ReBr (CO) 5 in moderate to good yields.

Related Articles:

Aldol Condensation of Esters with Ketones or Aldehydes to Form β-Hydroxy Esters by Lithium Amide. Comparison with the Reformatsky Reaction1

[Hauser; Puterbaugh Journal of the American Chemical Society, 1953 , vol. 75, p. 1068,1069, 1071]

Reduction of substituted. DELTA. 2-isoxazolines. Synthesis of. beta.-hydroxy acid derivatives

[Curran, Dennis P.; Scanga, Susan A.; Fenk, Christopher J. Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3474 - 3478]

Reformatsky reactions with SmI 2 in catalytic amount

[Orsini, Fulvia; Lucci, Elvira Maria Tetrahedron Letters, 2005 , vol. 46, # 11 p. 1909 - 1911]

Reduction of substituted. DELTA. 2-isoxazolines. Synthesis of. beta.-hydroxy acid derivatives

[Curran, Dennis P.; Scanga, Susan A.; Fenk, Christopher J. Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3474 - 3478]

Titanium-catalyzed Reformatsky-type reaction

[Sgreccia, Laura; Bandini, Marco; Morganti, Stefano; Quintavalla, Arianna; Umani-Ronchi, Achille; Cozzi, Pier Giorgio Journal of Organometallic Chemistry, 2007 , vol. 692, # 15 p. 3191 - 3197]

More Articles...