The Synthesis and Some Reactions of Diazocyclobutane1

DE Applequist, DE McGreer

Index: Applequist,D.E.; McGreer,D.E. Journal of the American Chemical Society, 1960 , vol. 82, p. 1965 - 1972

Full Text: HTML

Citation Number: 24

Abstract

L) iamcyclobutatic 11as been prepared by the reaction of N-cyclobutyl-nT-nitrosourea with alkoxides. lhe diazo corup~ und f (lrms-yclol~ utaiione azine on thermal decomposition, cyclobutyl phenyl ketone on reaction with bcnzaldehydc, and a mixture of ethyl spirohexane- 1-carboxylate and ethyl@-cyclobutylacrylates on reaction with ethyl acrylate. The reactions of the diazo compound with carboxylic acids in ether give mixtures of products which ...