2-Iodylphenol ethers: preparation, X-ray crystal structure, and reactivity of new hypervalent iodine (V) oxidizing reagents

…, IM Geraskin, VN Nemykin, VV Zhdankin

Index: Koposov, Alexey Y.; Karimov, Rashad R.; Geraskin, Ivan M.; Nemykin, Victor N.; Zhdankin, Viktor V. Journal of Organic Chemistry, 2006 , vol. 71, # 22 p. 8452 - 8458

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Citation Number: 38

Abstract

2-Iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenol ethers and isolated as chemically stable, microcrystalline products. Single- crystal X-ray diffraction analysis of 1-iodyl-2-isopropoxybenzene 8c and 1-iodyl-2- butoxybenzene 8d revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO2 groups of different molecules. 2-Iodylphenol ...