Group 14 organometallic reagents. 9. Organotin-mediated monoacylation of diols with reversed chemoselectivity: a convenient synthetic method

…, A Ricci, S Roelens, S Scapecchi

Index: Reginato, Gianna; Ricci, Alfredo; Roelens, Stefano; Scapecchi, Serena Journal of Organic Chemistry, 1990 , vol. 55, # 17 p. 5132 - 5139

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Citation Number: 63

Abstract

The organotin-mediated monoesterification of unsymmetrical diols with reversed chemoselectivity has been explored to ascertain scope and limits of the method and to provide an easy and convenient synthetic procedure. The reaction has been performed on a set of substituted diols with some acylating agents usually employed as protecting groups. Two different procedures have been devised to obtain either the desired diol monoesters ...