Preparation of functionalized arylmagnesium reagents bearing an o-chloromethyl group

…, L Bérillon, G Cahiez, P Knochel

Index: Delacroix; Berillon; Cahiez; Knochel Journal of Organic Chemistry, 2000 , vol. 65, # 23 p. 8108 - 8110

Full Text: HTML

Citation Number: 49

Abstract

The iodine-magnesium exchange is a unique method for the preparation of polyfunctional organomagnesium reagents. 1, 2 The efficient reaction of i-PrMgX with a wide range of functionalized aryl iodides proceeds under mild conditions so that various sensitive functional groups such as an ester, a nitrile, or an amide function are tolerated during the organomagnesium reagent formation. This method complements nicely the classical ...

Related Articles:

Direct One-Pot Cobalt (II) Phthalocyanine Catalyzed Synthesis of N-Substituted Isoindolinones

[Kumar, Vishal; Sharma, Upendra; Singh, Bikram; Kumar, Neeraj Australian Journal of Chemistry, 2012 , vol. 65, # 12 p. 1594 - 1598]

Highly efficient synthesis of N-substituted isoindolinones and phthalazinones using Pt nanowires as catalysts

[Organic Letters, , vol. 14, # 7 p. 1876 - 1879]

Divergent Palladium Iodide Catalyzed Multicomponent Carbonylative Approaches to Functionalized Isoindolinone and Isobenzofuranimine Derivatives

[Ordonez, Mario; Tibhe, Gaurao D.; Zamudio-Medina, Angel; Viveros-Ceballos, Jose Luis Synthesis, 2012 , vol. 44, # 4 p. 569 - 574]

Efficient synthesis of 1, 4-diaryl-5-methyl-1, 2, 3-triazole, a potential mGluR1 antagonist, and the risk assessment study of arylazides

[Tsuritani, Takayuki; Kii, Satoshi; Akao, Atsushi; Sato, Kimihiko; Nonoyama, Nobuaki; Mase, Toshiaki; Yasuda, Nobuyoshi Synlett, 2006 , # 5 p. 801 - 803]

2??Phenylphthalimidine derivatives. A probable formation mechanism of adducts from 3??benzylidenephthalide and aniline

[Journal of Heterocyclic Chemistry, , vol. 21, # 5 p. 1499 - 1503]

More Articles...