Aspects of catalytic hydrogenation with a soluble catalyst

AJ Birch, KAM Walker

Index: Birch,A.J.; Walker,K.A.M. Journal of the Chemical Society [Section] C: Organic, 1966 , p. 1894 - 1896

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Citation Number: 47

Abstract

The use of tristriphenylphosphinerhodium chloride as a soluble catalyst for hydrogenation has been further investigated, and some of its specificities have been examined in systems containing more than one double bond. Its properties include the ability to add deuterium specifically to the double bonds of cyclohexene, oleic and linoleic acids, and ergosterol without introduction of additional labelling. Some hydrogenations without hydrogenolysis ...