Addition Reactions to Methylenecyclopropanes II: Electrophilic Additions of Diphenylmethylenecyclopropane
E Dunkelblum
Index: Dunkelblum,E. Israel Journal of Chemistry, 1973 , vol. 11, # 4 p. 557 - 566
Full Text: HTML
Citation Number: 10
Abstract
Abstract A number of addition reactions to diphenylmethylenecyclopropane (II) have been studied. Bromination and CF 3 COOH addition in CH 3 Cl 2 proceeded with ring-opening and gave the homoallylic adducts III and VI. On the other hand bromination in glyme and water gave both unrearranged and rearranged products, III and V. Reactions with NBS in the same solvent system gave the unrearranged bromohydrin V. Oxymercuration and ...
Related Articles:
One-pot method for α-phenylation of ketones using isoxazolidine and triphenylaluminum
[Miyoshi, Tetsuya; Sato, Shohei; Tanaka, Hiroya; Hasegawa, Chihiro; Ueda, Masafumi; Miyata, Okiko Tetrahedron Letters, 2012 , vol. 53, # 32 p. 4188 - 4191]
[Brodhag; Hauser Journal of the American Chemical Society, 1955 , vol. 77, p. 3024,3030]
Reaction of diaziridines with diphenylketene and isocyanates
[Komatsu,M. et al. Journal of Organic Chemistry, 1974 , vol. 39, p. 3198 - 3205]
[Trimitsis, G. B.; Hinkley, J. M.; TenBrink, R.; Faburada, A. L.; Anderson, R.; et al. Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 2957 - 2962]
Reaction of diaziridines with diphenylketene and isocyanates
[Komatsu,M. et al. Journal of Organic Chemistry, 1974 , vol. 39, p. 3198 - 3205]