t-Carbinamines, RR'R ″CNH2. III. The Preparation of Isocyanates, Isothiocyanates and Related Compounds1
N Bortnick, LS Luskin, MD Hurwitz…
Index: Bortnick et al. Journal of the American Chemical Society, 1956 , vol. 78, p. 4358,4360
Full Text: HTML
Citation Number: 35
Abstract
Thermal dissociation of carbamates to isocyanates and alcohols is difficult and requires temperatures above 250'. The lower N-alkylcarbamates, which distil without decomposition under atmospheric pressure, must therefore be cracked in vapor phase operation. 2 The requisite temperatures for liquid phase cleavage can be attained by the distillation of esters of high boiling alcohols. 2 Although Raney nickel effects the cleavage of urethans, it has ...
Related Articles:
Studies of methyl isocyanate chemistry in the Bhopal incident
[D'Silva, Themistocles D. J.; Lopes, Anibal; Jones, Russell L.; Singhawangcha, Sureerat; Chan, John K. Journal of Organic Chemistry, 1986 , vol. 51, # 20 p. 3781 - 3788]
Synthesis of isomelamines and isocyanurates and their biological evaluation.
[Niwa, Ryuji; Kamada, Hitoshi; Shitara, Eiki; Horiuchi, Jiro; Kibushi, Nobuyuki; Kato, Tetsuzo Chemical and Pharmaceutical Bulletin, 1996 , vol. 44, # 12 p. 2314 - 2317]
Studies on Triazines. I. Reaction of Isocyanuric Ester with Organomagnesium Compounds
[Sobotka; Bloch Journal of the American Chemical Society, 1937 , vol. 59, p. 2606]
Thiacyclophane cages and related Bi-and tripodal molecules via transient polysulfenic acids
[Tripolt, Robert; Nachbaur, Edgar Phosphorus, Sulfur and Silicon and the Related Elements, 1992 , vol. 65, # 1.4 p. 173 - 176]
[Kaftory, Menahem; Botoshansky, Mark; Kapon, Moshe; Shteiman, Vitaly Acta Crystallographica Section B: Structural Science, 2001 , vol. 57, # 6 p. 791 - 799]