Synthesis

Nucleophile Acylierung mit 2-Lithium-1, 3-dithianen bzw.-1, 3, 5-trithianen1, 2, 3

D Seebach

Index: Seebach,D. Synthesis, 1969 , p. 17 - 36

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Citation Number: 428

Abstract

Nucleophile Acylierungen sind Reaktionen, bei denen eine Acylgruppe als Nucleophil mit einem elektrophilen Partner reagiert. Im Gegensatz zu den klassischen elektrophilen Acylierungsmitteln, wie Carbonsäurechloriden,-bromiden ‚-estern,-amiden und-nitrilen ‚ist ein Molekül mit nucleophilem Carbonyl-C-Atom ungewöhnlich, da man mit der Carbonylgruppe instinktiv ein elektrophilcs C-Atom assoziiert.

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