Journal of Organometallic Chemistry

Organometallic compounds: LXIX. Synthesis and properties of the first chiral triorganostannyl-manganese complex

M Gielen, IV Eynde

Index: Gielen, Marcel; Eynde, Ivan Vanden Journal of Organometallic Chemistry, 1981 , vol. 217, # 2 p. 205 - 213

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Abstract

Abstract Methyl-1-naphthylphenylstannyltetracarbonyl (diphenyl-N-methyl-N-(S)-1- phenylethylaminophosphine) manganese (I) has been prepared by two different routes from racemic methyl-1-naphthylphenyltin chloride. Fractional recrystallizations yielded two diastereomeric fractions with fx205-1=+ 40.3 and—71.4, respectively, which have identical NMR and IR spectra.