The Journal of Organic Chemistry

Medium-Ring Systems. 6.1 Synthesis and Isomerizations of Medium-Ring 3-Methylenecycloalkanones and 3-Methylcycloalkenones

P Eskola, JA Hirsch

Index: Ohloff et al. Chemische Berichte, 1956 , vol. 89, p. 1549,1553

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Citation Number: 5

Abstract

... Volume: Page: ... the appropriate 3-carbomethoxycycloalkenone 4, 1,9-11,14 the ketone was protected as the ethylene ketal 5 using PPTS 15 or p-TsOH ... the allylic alcohol 6 was performed using alcoholic LiAlH 4 17 or, preferably, DIBALH 18 in CH 2 Cl 2 or Et 2 O ...