The synthesis, electrochemical and fluorescent properties of monomers and polymers containing 2, 5-diphenyl-1, 3, 4-thiadiazole
Y Tao, Q Xu, J Lu, X Yang
Index: Tao, Yongxin; Xu, Qingfeng; Lu, Jianmei; Yang, Xuebo Dyes and Pigments, 2010 , vol. 84, # 2 p. 153 - 158
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Citation Number: 15
Abstract
Three, 2, 5-diphenyl-1, 3, 4-thiadiazole-containing vinyl monomers and their polymers were synthesized and the HOMO and LUMO energies of the compounds, as estimated from cyclic voltammetry data, were− 6.35 to− 6.14 eV and− 3.02 to− 2.84 eV, respectively. The optical band gaps (Eg) were similar to those determined from cyclic voltammograms. The fluorescent emission spectra of all monomers and polymers displayed either blue or green ...
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