β-Benzohydrylglutaric Acid

MS Newman, LM Joshel, PH Wise

Index: Newman; Joshel; Wise Journal of the American Chemical Society, 1940 , vol. 62, p. 1861

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Abstract

Since this experiment indicated that the double bond in I would not readily shift to the a,@- position, it seemed advisable to employ as starting material a compound in which the double bond was fixed in the desired position. Accordingly sodiomalonic ester was condensed with the lactone of y-hydroxy-y, y-diphenylcrotonic acid 111," to yield the lactone of 8-( whydroxybenzohydry1)-glutaric acid, IV. The same end-product was obtained if j3-bromo- ...