Ketone synthesis via palladium-catalyzed carbonylation of organoaluminium compounds
NA Bumagin, AB Ponomaryov, IP Beletskaya
Index: Bumagin, N. A.; Ponomaryov, A. B.; Beletskaya, I. P. Tetrahedron Letters, 1985 , vol. 26, # 39 p. 4819 - 4822
Full Text: HTML
Citation Number: 78
Abstract
Table.1. Reactions of RAlRi (0.75 mmol) with R"X (0.5 mmol) and car- bon monoxide (1 atm) in the presence of PdC12(MeCN)2 (0.05 mmol) 1 ... R R' RNX Solventa T,'C Yieldb', % ... Ph Ph p-N02C6H41 A 50 1 ... ---a_-------------- Ph i-Bu ~-N02C6H41 C 50 4Omin ... CH2=CH- i-Bu p-N02C6H41 E 30 40min ... 20 min, then it was allowed to cool down to room temperature. The reaction flask was filled with carbon monoxide with intensive stirring. ...
Related Articles:
Synthesis of 4-and 6-substituted nitroindoles
[Moskalev, Nikolai; Barbasiewicz, Michal; Makosza, Mieczyslaw Tetrahedron, 2004 , vol. 60, # 2 p. 347 - 358]
Synthesis of novel substituted diaryl-1, 4-diazepines
[Ramajayam; Giridhar, Rajani; Yadav Chemistry of Heterocyclic Compounds, 2006 , vol. 42, # 7 p. 901 - 906]
[Xu, Qing-Long; Gao, Hongyin; Yousufuddin, Muhammed; Ess, Daniel H.; Kuerti, Laszlo Journal of the American Chemical Society, 2013 , vol. 135, # 38 p. 14048 - 14051]
A novel nucleophilic substitution of the formyl group in p-nitrobenzaldehyde with some carbanions
[Iwasaki, Genji; Saeki, Seitaro; Hamana, Masatomo Chemistry Letters, 1986 , p. 173 - 176]
[Soria-Castro, Silvia M.; Caminos, Daniel A.; Penenory, Alicia B. RSC Advances, 2014 , vol. 4, # 34 p. 17490 - 17497]