Ketene Acetals. XXXIV. Tetra-and Pentamethylene Ketene Acetals

SM McElvain, RE Starn Jr

Index: McElvain; Starn Journal of the American Chemical Society, 1955 , vol. 77, p. 4571,4577

Full Text: HTML

Citation Number: 25

Abstract

Ketene acetals VI11 and VIIIa with the nucleophilic center in a cyclopentane and cyclohexane ring have been prepared by the dealcoholation of the corresponding orthoesters VI1 and VIIa. These dealcoholations proceed in satisfactory yields only with sublimed aluminum t-butoxide. Methyl and t-butyl normal esters are significant reaction products and evidence is presented as to their mode of formation. Attempts to prepare the ...

Detail

Gold activation of nitriles: Catalytic hydration to amides

[Ramon, Ruben S.; Marion, Nicolas; Nolan, Steven P. Chemistry - A European Journal, 2009 , vol. 15, # 35 p. 8695 - 8697]

Chlorosulfonyl isocyanate addition to bicyclo [2.1. 0] penta...

[Moriconi,E.J.; Dutta,C.P. Journal of Organic Chemistry, 1970 , vol. 35, p. 2443 - 2445]

Heteroalicyclic carboxamidines as inhibitors of inducible ni...

[Young, Robert J.; Alderton, Wendy; Angell, Anthony D.R.; Beswick, Paul J.; Brown, David; Chambers, C. Lynn; Crowe, Miriam C.; Dawson, John; Hamlett, Christopher C.F.; Hodgson, Simon T.; Kleanthous, Savvas; Knowles, Richard G.; Russell, Linda J.; Stocker, Richard; Woolven, James M. Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 10 p. 3037 - 3040]

Cyclopropanecarboxylic acid fluoride. Improved synthesis

[Dear,R.E.A.; Gilbert,E.E. Journal of Organic Chemistry, 1968 , vol. 33, p. 1690 - 1692]

Cyclische Diazoverbindungen, V: Ein Diazoketon mit Dreirings...

[Schmitz,E. et al. Chemische Berichte, 1965 , vol. 98, p. 2509 - 2515]