Synthesis of aryl perfluoroalkyl sulfides from aromatic disulfides

…, SA Kashtanov, VA Potemkin, JS Thrasher…

Index: Sipyagin; Enshov; Kashtanov; Potemkin; Thrasher; Waterfeld Russian Chemical Bulletin, 2004 , vol. 53, # 2 p. 420 - 434

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Citation Number: 4

Abstract

Abstract Thermolysis of xenon (ii) bis (perfluoroalkanecarboxylates) in the presence of diaryl disulfides occurs through the S—S bond cleavage to form dihalo-, halonitro-, and halodinitrophenyl perfluoroalkyl sulfides. The latter type of compounds was obtained for the first time. The main side process is the perfluoroalkylation of the aromatic ring.