Chemical Communications

Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

TT Wang, FX Wang, FL Yang, SK Tian

Index: Wang, Ting-Ting; Wang, Fu-Xiang; Yang, Fu-Lai; Tian, Shi-Kai Chemical Communications, 2014 , vol. 50, # 29 p. 3802 - 3805

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Citation Number: 24

Abstract

A range of highly enantioenriched primary allylic amines underwent palladium-catalyzed oxidative coupling with sulfonyl hydrazides open to air at room temperature to give structurally diverse allylic sulfones in moderate to excellent yields with excellent retention of ee.